N Nitrogen: Compounds with Noble Gases and HydrogenWalter Hack, Reinhard Haubold, Ulrike Ohms-Bredemann, Claudia Heinrich-Sterzel, Hannelore Keller-Rudek, Dag Schiöberg, Carol Strametz Springer Science & Business Media, 2013年6月29日 - 280 頁 "Nitrogen" Suppt. Vol. B 1 describes the compounds of nitrogen with noble gases and, in the major part, binary compounds composed of one nitrogen atom and hydrogen. Nitrogen hydrogen compounds with two and more nitrogen atoms are covered in "Nitrogen" Suppt. Vol. 82. There is some information on various nitrogen-noble gas species, to a large extent because of the interest in their bonding behavior. Experimental data have been obtained chiefly for some singly charged cations, particularly those formed by argon Like ArN + and ArNi. The existence of others has only been established by mass spectrometry. The binary compounds of nitrogen and hydrogen comprise NH, NH , NH , NH , the corre 2 4 5 sponding ions, and some adducts. NH and NH1 are not treated. The predominant part 3 of the volume covers the description of the molecules NH and NH . 8oth species are present 2 in photolytic processes in the atmosphere. They play an essential role in combustion systems regardless of whether the nitrogen stems from the nitrogen-containing fuel or from the air. Thus, much work has been devoted to the understanding of the nitrogen chemistry in combustion and in the atmosphere. The production and detection methods as weiL as the reactions have been comprehensively described. ln addition detailed information is given on the spectral behavior, the knowledge of which is important for detecting the mole cules and for studying their kinetics. |
內容
1 | |
Compounds of Nitrogen with Hydrogen | 14 |
Molecular Vibrations | 186 |
Enthalpy of Formation Thermodynamic Functions | 193 |
In Condensed Phases | 251 |
258 | |
268 | |
Physical Constants and Conversion Factors | 279 |
其他版本 - 查看全部
常見字詞
¹II ¹Σ ²II ³II ³Σ ³П à 2A ab initio absorption activation energy ammonia Ashfold Astrophys CAS Registry CAS Registry Number Chem Chim cm¯¹ cm¹ cm³ collisions Combust derived detected discharge dissociation electron impact electronic ground emission spectrum experimental flames flash photolysis flow reactor fluorescence formation Gmelin Handbook H atoms H₂ H₂O Hack high-resolution HNCO hyperfine initio calculations intersystem crossing ionization ionization potential kinetic kJ/mol laser photolysis Lett lifetime Mass Spectrom matrix mbar measured Molecular molecules N₂ ND(a NH and ND NH(a NH(a ¹A NH(c NH(X NH₂ NH₂ radicals nitrogen observed obtained perturbation Peyerimhoff photolysis of NH3 Phys Proc quenching Ramsay rate constant reaction REMPI resonance room temperature rotational levels Rydberg shock tube spectra Spectrosc studies Stuhl Symp temperature range transitions Tsunashima values Vervloet vibrational