Syntheses and Physical Studies of Inorganic Compounds

absorption bands acetate Acta adduct AlCl3 aluminium chloride Amer anhydrous aqueous solution assigned astatine axial axial bonds axis bending benzene bis(benzene bond angle bond length borazine boron bridge carbon carbonyl Chem chemical shift chromium chromium(II cm-¹ complex compounds configuration containing coordination crystal cyclopentadienyl decomposition diborane dimer dissociation electron diffraction energy equatorial ethylenediamine experimental ferrocene fluorine formation frequencies fundamental vibrations H H H halides heating hybrid hydrogen infrared infrared spectrum Inorg inorganic interaction iron atom iron pentacarbonyl isomers kJ mol-¹ ligand liquid lone pair magnetic metal atom mixture molecular orbitals molecule nitrate nitric nitrogen nitrous acid NO₂ nucleus observed octahedral oxidation oxygen perchloric acid phosphorus Phys planar plane polarized properties proton quadrupole Raman spectrum reaction resonance rhenium room temperature rotation shows solid solvent spectra splitting stretch structure studies sulphur trioxide symmetry tetrahedral transition trigonal valence values vapour vibrational spectrum X-ray diffraction XeF4 xenon