Syntheses and Physical Studies of Inorganic Compounds
Syntheses and Physical Studies of Inorganic Compounds focuses on inorganic chemistry, covering the detailed physical and chemical properties of specific compounds with the emphasis on the application of physical principles, investigational techniques, and theoretical interpretation of experimental data. This book considers, in some depth, the synthesis, properties, reactions, and structures of a number of compounds that are selected on the criterion that the study of each has resulted in important contributions to the practice and understanding of inorganic chemistry. The details of exp
1 online resource (238 pages)
9781483280608, 1483280608
1058350809
Front Cover; Syntheses and Physical Studies of Inorganic Compounds; Copyright Page; Table of Contents; Dedication; PREFACE; CHAPTER 1. DIBORANE; Introduction; Preparation; Reactions; Structure; Vibrational Spectra; N.M.R. Spectra; Thermochemical Data; Bonding; References; CHAPTER 2. BORAZINE; Introduction; Preparation; Reactions; Structure; Vibrational Spectrum; N.M.R. Spectra; Bonding; References; CHAPTER 3. ALUMINIUM CHLORIDE; Introduction; Preparation; Reactions; Structure; Vibrational Spectrum; Aqueous Solutions of Aluminium Chloride; Energetics of Adduct Formation by Aluminium Chloride. BondingReferences; CHAPTER 4. NITROGEN DIOXIDE; Introduction; Preparation; Properties; Dinitrogen Tetroxide Solvent System; Reactions of Nitrogen Dioxide with Water and Alcohols; Spectroscopic Studies and Structure of NO2; Structure of Dinitrogen Tetroxide; E.S.R. Spectrum; Bonding; References; CHAPTER 5. TRISILYLAMINE; Introduction; Preparation; Reactions; Structure; Vibrational Spectrum; N.M.R. Spectrum; Bonding; References; CHAPTER 6. NITROUS ACID; Introduction; Preparation; Stability in Aqueous Solution; Reactions; Nitrous Acid Molecules; Dissociation Constant of Nitrous Acid. Isomers of Nitrous AcidReferences; CHAPTER 9. PHOSPHONITRILIC CHLORIDES; Introduction; Preparation; Reactions of (PNCl2)3 and (PNCl2)4; Structure of (PNCl2)4; Vibrational Spectra of (PNCI2)3 and (PNC12); N.Q.R. Spectra; N.M.R. Spectra; Bonding; References; CHAPTER 10. SULPHUR TETRAFLUORIDE; Introduction; Preparation; Reactions; Vibrational Spectrum; Structure; N.M.R. Spectra; Molecular Association of Sulphur Tetrafluoride; Bonding; References; CHAPTER 11. SULPHUR TRIOXIDE; Introduction; Preparation; Reactions; Structure; Stabilization of Liquid Sulphur Trioxide. Structure in the Gaseous and Liquid StatesReferences; CHAPTER 12. TETRASULPHUR TETRANITRIDE; Introduction; Preparation of S4N4 and Other S, N Compounds; Reactions; Structure of S4N4; Vibrational Spectra of S4N4 and S2N2; Strength of Sulphur-Nitrogen Bonds; Dipole Moment; Bonding; References; CHAPTER 13. PERCHLORIC ACID; Introduction; Preparation; Reactions; Molecular Structure of Anhydrous Perchloric Acid; Hydrates of Perchloric Acid; Structure of Perchloric Acid Monohydrate; Structure of Perchloric Acid Dihydrate; Vibrational Spectra; Ionic Rotation in HClO4 · H2O. Dissociation of Perchloric AcidAcidity Function of Perchloric Acid; References; CHAPTER 14. XENON TETRAFLUORIDE; Introduction; Preparation; Reactions; Structure; Vibrational Spectra; Mössbauer Spectra; Theories of Bonding; References; CHAPTER 15. CHROMIUM(II) ACETATE; Introduction; Preparation and Reactions; Structure; References; CHAPTER 16. DIBENZENE CHROMIUM; Introduction; Preparation; Reactions; Structure; Vibrational Spectrum; Electronic Absorption Spectrum; Bonding; References; CHAPTER 17. MOLYBDENUM(II) CHLORIDE; Introduction; Preparation; Reactions; Structure; Vibrational Spectrum
Comparative Properties of Molybdenum Chlorides